Chloro(meso-tetrapropylporphyrinato)iron(III)

Yoshiki Ohgo; Takahisa Ikeue; Mikio Nakamura

doi:10.1107/S0108270199009312

Chloro(meso-tetrapropylporphyrinato)iron(III)

Yoshiki Ohgo, Takahisa Ikeue, Mikio Nakamura

Toho University

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

In the chloroiron(III) complex of meso-tetrapropylporphyrin, [Fe(C₃₂H₃₆N₄)Cl], the Fe^III atom has slightly distorted square-pyramidal coordination. The porphyrin ring shows a typical S₄-ruffled structure in addition to a normally observed domed core; the deviations of the meso-C and Fe atoms from the least-squares plane of the C₂₀N₄ core are 0.366(4) (maximum) and 0.578(1) Å, respectively. The average Fe - N_p bond distance is 2.063 (4) Å.

Original language	English
Pages (from-to)	1817-1819
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	55
Issue number	11
DOIs	https://doi.org/10.1107/S0108270199009312
State	Published - 15 Nov 1999
Externally published	Yes

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title = "Chloro(meso-tetrapropylporphyrinato)iron(III)",

abstract = "In the chloroiron(III) complex of meso-tetrapropylporphyrin, [Fe(C32H36N4)Cl], the FeIII atom has slightly distorted square-pyramidal coordination. The porphyrin ring shows a typical S4-ruffled structure in addition to a normally observed domed core; the deviations of the meso-C and Fe atoms from the least-squares plane of the C20N4 core are 0.366(4) (maximum) and 0.578(1) {\AA}, respectively. The average Fe - Np bond distance is 2.063 (4) {\AA}.",

author = "Yoshiki Ohgo and Takahisa Ikeue and Mikio Nakamura",

year = "1999",

month = nov,

day = "15",

doi = "10.1107/S0108270199009312",

language = "英語",

volume = "55",

pages = "1817--1819",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "John Wiley & Sons Inc.",

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T1 - Chloro(meso-tetrapropylporphyrinato)iron(III)

AU - Ohgo, Yoshiki

AU - Ikeue, Takahisa

AU - Nakamura, Mikio

PY - 1999/11/15

Y1 - 1999/11/15

N2 - In the chloroiron(III) complex of meso-tetrapropylporphyrin, [Fe(C32H36N4)Cl], the FeIII atom has slightly distorted square-pyramidal coordination. The porphyrin ring shows a typical S4-ruffled structure in addition to a normally observed domed core; the deviations of the meso-C and Fe atoms from the least-squares plane of the C20N4 core are 0.366(4) (maximum) and 0.578(1) Å, respectively. The average Fe - Np bond distance is 2.063 (4) Å.

AB - In the chloroiron(III) complex of meso-tetrapropylporphyrin, [Fe(C32H36N4)Cl], the FeIII atom has slightly distorted square-pyramidal coordination. The porphyrin ring shows a typical S4-ruffled structure in addition to a normally observed domed core; the deviations of the meso-C and Fe atoms from the least-squares plane of the C20N4 core are 0.366(4) (maximum) and 0.578(1) Å, respectively. The average Fe - Np bond distance is 2.063 (4) Å.

UR - http://www.scopus.com/inward/record.url?scp=0003625298&partnerID=8YFLogxK

U2 - 10.1107/S0108270199009312

DO - 10.1107/S0108270199009312

M3 - 記事

AN - SCOPUS:0003625298

SN - 0108-2701

VL - 55

SP - 1817

EP - 1819

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 11

ER -

Chloro(meso-tetrapropylporphyrinato)iron(III)

Abstract

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