Assignment of the absolute configuration of blasticidin A and revision of that of aflastatin A

Shohei Sakuda; Nobuaki Matsumori; Kazuo Furihata; Hiromichi Nagasawa

doi:10.1016/j.tetlet.2007.02.024

Assignment of the absolute configuration of blasticidin A and revision of that of aflastatin A

Shohei Sakuda
, Nobuaki Matsumori
, Kazuo Furihata
, Hiromichi Nagasawa

The University of Tokyo
The University of Osaka

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The absolute configuration of blasticidin A, a strong inhibitor of aflatoxin production by Aspergillus parasiticus, was assigned by adding the data of relative configurations at its diol and pentaol moieties to previously known stereochemistry. Similarity of the NMR data of blasticidin A to those of aflastatin A allowed us to revise the stereochemistry of the diol and pentaol moieties of aflastatin A.

Original language	English
Pages (from-to)	2527-2531
Number of pages	5
Journal	Tetrahedron Letters
Volume	48
Issue number	14
DOIs	https://doi.org/10.1016/j.tetlet.2007.02.024
State	Published - 2 Apr 2007
Externally published	Yes

Keywords

Absolute configuration
Aflastatin A
Aflatoxin
Blasticidin A

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10.1016/j.tetlet.2007.02.024

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abstract = "The absolute configuration of blasticidin A, a strong inhibitor of aflatoxin production by Aspergillus parasiticus, was assigned by adding the data of relative configurations at its diol and pentaol moieties to previously known stereochemistry. Similarity of the NMR data of blasticidin A to those of aflastatin A allowed us to revise the stereochemistry of the diol and pentaol moieties of aflastatin A.",

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AU - Sakuda, Shohei

AU - Matsumori, Nobuaki

AU - Furihata, Kazuo

AU - Nagasawa, Hiromichi

PY - 2007/4/2

Y1 - 2007/4/2

N2 - The absolute configuration of blasticidin A, a strong inhibitor of aflatoxin production by Aspergillus parasiticus, was assigned by adding the data of relative configurations at its diol and pentaol moieties to previously known stereochemistry. Similarity of the NMR data of blasticidin A to those of aflastatin A allowed us to revise the stereochemistry of the diol and pentaol moieties of aflastatin A.

AB - The absolute configuration of blasticidin A, a strong inhibitor of aflatoxin production by Aspergillus parasiticus, was assigned by adding the data of relative configurations at its diol and pentaol moieties to previously known stereochemistry. Similarity of the NMR data of blasticidin A to those of aflastatin A allowed us to revise the stereochemistry of the diol and pentaol moieties of aflastatin A.

KW - Absolute configuration

KW - Aflastatin A

KW - Aflatoxin

KW - Blasticidin A

UR - https://www.scopus.com/pages/publications/33847628441

U2 - 10.1016/j.tetlet.2007.02.024

DO - 10.1016/j.tetlet.2007.02.024

M3 - 記事

AN - SCOPUS:33847628441

SN - 0040-4039

VL - 48

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EP - 2531

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 14

ER -

Assignment of the absolute configuration of blasticidin A and revision of that of aflastatin A

Abstract

Keywords

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