An isocyanide probe for heme electronic structure: Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d xy)2(dxz, dyz)3 ground state

Yoshiki Ohgo; Saburo Neya; Hidehiro Uekusa; Mikio Nakamura

doi:10.1039/b609910f

An isocyanide probe for heme electronic structure: Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d _xy)²(d_xz, d_yz)³ ground state

Yoshiki Ohgo
, Saburo Neya
, Hidehiro Uekusa
, Mikio Nakamura

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Isocyanide-bound model hemes always adopt the (d_xz, d _yz)⁴(d_xy)¹ ground state, however, we have found that the replacement of porphyrin by diazaporphyrin leads to the formation of an unprecedented low-spin bis(tert-butylisocyanide) complex with the (d_xy)²(d_xz, d_yz)³ ground state.

Original language	English
Pages (from-to)	4590-4592
Number of pages	3
Journal	Chemical Communications
Issue number	44
DOIs	https://doi.org/10.1039/b609910f
State	Published - 2006
Externally published	Yes

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title = "An isocyanide probe for heme electronic structure: Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d xy)2(dxz, dyz)3 ground state",

abstract = "Isocyanide-bound model hemes always adopt the (dxz, d yz)4(dxy)1 ground state, however, we have found that the replacement of porphyrin by diazaporphyrin leads to the formation of an unprecedented low-spin bis(tert-butylisocyanide) complex with the (dxy)2(dxz, dyz)3 ground state.",

author = "Yoshiki Ohgo and Saburo Neya and Hidehiro Uekusa and Mikio Nakamura",

year = "2006",

doi = "10.1039/b609910f",

language = "英語",

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journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - An isocyanide probe for heme electronic structure

T2 - Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d xy)2(dxz, dyz)3 ground state

AU - Ohgo, Yoshiki

AU - Neya, Saburo

AU - Uekusa, Hidehiro

AU - Nakamura, Mikio

PY - 2006

Y1 - 2006

N2 - Isocyanide-bound model hemes always adopt the (dxz, d yz)4(dxy)1 ground state, however, we have found that the replacement of porphyrin by diazaporphyrin leads to the formation of an unprecedented low-spin bis(tert-butylisocyanide) complex with the (dxy)2(dxz, dyz)3 ground state.

AB - Isocyanide-bound model hemes always adopt the (dxz, d yz)4(dxy)1 ground state, however, we have found that the replacement of porphyrin by diazaporphyrin leads to the formation of an unprecedented low-spin bis(tert-butylisocyanide) complex with the (dxy)2(dxz, dyz)3 ground state.

UR - https://www.scopus.com/pages/publications/33750602305

U2 - 10.1039/b609910f

DO - 10.1039/b609910f

M3 - 記事

C2 - 17082852

AN - SCOPUS:33750602305

SN - 1359-7345

SP - 4590

EP - 4592

JO - Chemical Communications

JF - Chemical Communications

IS - 44

ER -

An isocyanide probe for heme electronic structure: Bis(tert- butylisocyanide) complex of diazaporphyrin showing a unique (d _xy)²(d_xz, d_yz)³ ground state

Abstract

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